The synthesis, characterization and theoretical study of nano tetrabuthylammonium trichloroiodoaluminate (III)

Ano: 2012 | Volume: 4 | Número: 3

Autores: Shahriar Ghammamy

Palavras-chave: nanoparticles, aluminate complex, xrd, theoretical calculation

Resumo Inglês:

There is provided a nano aluminate complex that has a quaternary ammonium
cation. This nano system has an equal molar ratio of Al to N that has been prepared by
reaction of an organic salt R
+
X
-
such as [(CH3)4NBr], and a Lewis acid such as AlCl3,
compounds. The synthesized compound was characterized by IR, Mass, X-Ray diffraction
measurements. In addition, the structure of synthesized compound was optimized at the
theoretical level of the Moller-Plesser perturbations of the second order (MP2), with
LanL2DZ basis set and molecular specifications such as band length and angle were
extracted using Gaussian 98 program. Theoretical data show good agreement with the
experimental result.